lithium bis(fluorosulfonyl)imide cas 171611-11-3

Chemical Name:Lithium Bis(fluorosulfonyl)imide(LiFSi)
CAS No.: 171611-11-3
Molecular Formula: F2NO4S2.Li
Molecular Weight:187.0721064
Appearance:White powder

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Table of Contents

Lithium Bis(fluorosulfonyl)imide (LiFSI) CAS 171611-11-3: Product Specifications

Basic Parameters

Parameter Value
CAS Number 171611-11-3
Molecular Formula LiN(SO2F)2
Molecular Weight 187.07 g/mol
Appearance White crystalline powder
Purity ≥99.9% (Battery Grade)
Density 1.78 g/cm³
Melting Point 145-150°C
Solubility Highly soluble in organic carbonates

Performance Comparison with Common Lithium Salts

Property LiFSI LiPF6 LiTFSI
Thermal Stability >200°C ≤70°C 180°C
Conductivity (1M in EC/DMC) 10.5 mS/cm 10.1 mS/cm 9.8 mS/cm
Aluminum Corrosion Non-corrosive Corrosive Moderate
Moisture Sensitivity Low High Moderate

Advanced Applications in Energy Storage Systems

1. High-Voltage Lithium-Ion Batteries

Enables stable operation above 4.4V through superior oxidation resistance. Recommended concentration: 0.5-1.5M in ternary solvent systems.

2. Solid-State Battery Electrolytes

Enhances ionic conductivity of polymer electrolytes (PEO-based) by 300% at 60°C when used as 15-20% additive.

3. Extreme-Temperature Supercapacitors

Maintains >90% capacitance retention from -40°C to 120°C in acetonitrile-based electrolytes.

Technical Handling Protocol

1. Storage Requirements

Store in argon-filled containers at ≤30°C/≤20% RH. Shelf life: 36 months in original packaging.

2. Electrolyte Formulation

Optimal performance achieved with 1:1:1 EC/PC/DMC solvent blend. Pre-dry solvents to ≤10ppm H2O before mixing.

3. Compatibility Matrix

Material Compatibility Notes
NMC Cathodes Excellent Reduces transition metal dissolution
Graphite Anodes Good Requires 5% FEC additive
Aluminum Current Collectors Superior No passivation needed

Documented Industry Implementations

Case 1: EV Battery Thermal Management

Client: Leading European EV Manufacturer
Challenge: Reduce thermal runaway risk in 811 NMC cells
Solution: 1.2M LiFSI in fluorinated electrolyte blend
Result: Passed nail penetration test at 45°C, cycle life increased to 2000+

Case 2: Aerospace Power Systems

Client: Satellite Power Supplier
Requirement: -60°C to +150°C operational range
Implementation: 0.8M LiFSI in sulfolane-based electrolyte
Outcome: 94% capacity retention after 500 thermal cycles

Technical Consultation & Ordering

Contact our electrolyte specialists for application-specific solutions:
Email: info@vivalr.com
Tel: (86) 15866781826

Request for Proposal Checklist

  • Target application (battery type/energy storage system)
  • Required purity level (99.9%/99.95%/99.99%)
  • Annual consumption estimate (kg/month)
  • Custom particle size requirements (D50/D90)
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