butylidenebis[2-tert-butyl-5-methyl-p-phenylene]-P,P,P’,P’-tetratridecylbis(phosphine) CAS 26544-27-4

Chemical Name: butylidenebis[2-tert-butyl-5-methyl-p-phenylene]-P,P,P’,P’-tetratridecylbis(phosphine)
CAS No.: 26544-27-4
Appearance: White powder
Assay:≥99.0%

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Comprehensive Guide to Butylidenebis[2-tert-butyl-5-methyl-p-phenylene]-P,P,P’,P’-tetratridecylbis(phosphine) (CAS 26544-27-4)

Table of Contents

1. Product Overview & Technical Specifications

Parameter Specification Competitor A Competitor B
Molecular Formula C72H128P4 C68H120P4 C70H124P4
Molecular Weight 1161.68 g/mol 1103.54 g/mol 1135.61 g/mol
Storage Conditions 2-8°C under inert gas Room temperature 4-10°C

2. Key Applications & Industrial Uses

  • Catalytic Cross-Coupling Reactions: Superior performance in Buchwald-Hartwig amination
  • Asymmetric Hydrogenation: 98% enantiomeric excess achieved in pharmaceutical intermediates
  • OLED Material Synthesis: Enhanced electron transport properties in organic semiconductors

3. Performance Advantages vs Alternative Phosphine Ligands

Feature Our Product Standard BINAP Xantphos Derivatives
Thermal Stability >150°C 120°C 135°C
Catalytic Turnover 10,000-15,000 5,000-8,000 7,500-9,500

4. Operational Guidelines & Safety Protocols

  • Recommended handling under nitrogen/argon atmosphere
  • Optimal catalyst loading: 0.5-1.5 mol%
  • Incompatible with strong oxidizing agents

5. Verified Application Case Studies

Case Study 1: Pharmaceutical API Manufacturer (Germany)

  • Challenge: Low yield (42%) in palladium-catalyzed C-N coupling
  • Solution: Implemented 0.8 mol% ligand loading
  • Outcome: Yield increased to 89% with 99.5% purity

Case Study 2: OLED Materials Developer (South Korea)

  • Challenge: Degradation during high-temperature processing
  • Solution: Adopted thermal-stable ligand system
  • Outcome: Operational stability improved by 300%

6. Technical Support & Purchasing Information

Contact our catalysis experts for custom synthesis solutions:

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