Lithium Hexafluorophosphate CAS 21324-40-3

Chemical Name: Lithium hexafluorophosphate
Synonyms: Lithium phosphorus fluoride
CAS No.: 21324-40-3
Molecular Formula: F6LiP
Molecular Weight: 151.91
Appearance: white powder

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Lithium Hexafluorophosphate (CAS 21324-40-3) Overview

Lithium Hexafluorophosphate (LiPF6), CAS 21324-40-3, is a critical lithium salt electrolyte widely used in lithium-ion batteries. Key properties:

Property Specification
Purity ≥99.9% (Battery Grade)
Appearance White crystalline powder
Moisture Content ≤20 ppm
Free Acid (HF) ≤50 ppm
Storage Temperature 2-8°C (under argon)

Comparative Analysis of LiPF6 Grades

Parameter Battery Grade Industrial Grade
Purity 99.95% 99.5%
Chloride (Cl⁻) ≤3 ppm ≤50 ppm
Sulfate (SO4²⁻) ≤5 ppm ≤100 ppm
Application High-performance batteries Chemical synthesis

Core Applications in Energy Storage

1. Lithium-ion Battery Electrolytes

As the dominant conductive salt (40-50% market share):

  • EV Batteries: Enhances cycle life up to 3,000 cycles @ 80% DoD
  • Consumer Electronics: Enables 4.4V+ high-voltage operation
  • ESS Solutions: Maintains conductivity at -30°C to 60°C

2. Specialty Chemical Synthesis

  • PF6⁻ source in organofluorine reactions
  • Catalyst in asymmetric synthesis

Operational Best Practices

Storage & Handling

  • Argon atmosphere with ≤10 ppm H2O
  • Stainless steel tools (avoid Al/Cu)

Electrolyte Formulation

Component Ratio Purpose
LiPF6 1.0-1.2M Conductive medium
EC:DEC 3:7 vol% Solvent system
VC 2% SEI improver

Verified Industry Implementations

Case 1: EV Battery Manufacturer

Client: Top 3 Chinese EV battery producer (2024 Q1 implementation)

  • Challenge: Thermal runaway above 60°C
  • Solution: Optimized LiPF6/LiFSI hybrid electrolyte
  • Result: 12%↑ energy density, 55°C thermal stability

Case 2: Consumer Electronics Giant

Client: Global smartphone leader (2023 partnership)

  • Requirement: Ultra-thin battery with 500 cycles
  • Implementation: 1.1M LiPF6 in EC:EMC (1:1)
  • Outcome: 0.5mm thickness achieved, 92% capacity retention

Technical Consultation & Custom Solutions

Our battery-grade LiPF6 meets:

  • ISO 9001:2015 & IATF 16949 certified
  • Batch-to-batch consistency: ±0.02% purity

Contact our electrolyte experts:

  • Email: info@vivalr.com
  • Tel: (86) 15866781826
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