2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene

Product Name:2
2′
7
7′-Tetrabromo-9
9′-spirobifluorene
CAS:128055-74-3
MFC25H12Br4
MW:631.98
EINECS:672-610-0
MOL File:128055-74-3.mol

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Guide to 2,2′,7,7′-Tetrabromo-9,9′-Spirobifluorene (TBSF)

Table of Contents

1. Product Overview & Specifications

2,2′,7,7′-Tetrabromo-9,9′-Spirobifluorene (TBSF) is a brominated spirobifluorene derivative widely used in optoelectronic materials. Key parameters include:

Parameter TBSF Similar Compound (SBF)
CAS Number 1255909-47-3 N/A
Molecular Formula C26H12Br4 C26H16
Molecular Weight 656.0 g/mol 328.4 g/mol
Purity ≥98% ≥95%
Thermal Stability Up to 300°C Up to 250°C

2. Applications of TBSF

  • OLED Materials: Acts as an electron-transport layer/hole-blocking layer to enhance device efficiency.
  • Photoinitiators: Used in UV-curable resins for 3D printing and coatings.
  • Flame Retardants: Bromine content improves fire resistance in polymers.
  • Pharmaceutical Intermediates: Building block for bioactive molecule synthesis.

3. Usage Guidelines

  • Safety: Use PPE (gloves, goggles) to avoid skin/eye contact. Handle under fume hood.
  • Storage: Keep in airtight containers at 2-8°C, protected from light.
  • Solubility: Soluble in THF, chloroform, and DCM; insoluble in water.
  • Processing: Optimize concentration (0.5-2 wt%) in OLED layers for balanced charge transport.

4. Case Studies

Case 1: TBSF in Flexible OLED Displays

A leading display manufacturer integrated TBSF into their red phosphorescent OLED stack, achieving:

  • 20% increase in external quantum efficiency (EQE)
  • 15% longer operational lifetime vs. non-brominated analogs

Case 2: High-Speed 3D Printing Resins

A 3D printing company used TBSF-based photoinitiators to:

  • Reduce curing time by 40% under 365 nm UV
  • Enable micron-scale resolution in dental aligner production

5. Client Success Stories

Client A: TechNova Materials

  • Challenge: Needed a thermally stable hole-blocking layer for blue OLEDs.
  • Solution: TBSF-doped HTL (10% concentration).
  • Result: 18% higher luminance efficiency; passed 85°C/85% RH reliability testing.
  • Quote: “TBSF gave us the performance edge our premium displays required.” – Dr. Lee, CTO

Client B: PolyLux Innovations

  • Challenge: Seeking low-migration photoinitiators for food-grade packaging inks.
  • Solution: TBSF-based formulation at 1.5 wt%.
  • Result: 99.9% polymerization efficiency; met EU 10/2011 compliance.
  • Quote: “Switching to TBSF slashed our regulatory approval time by 6 months.” – Ms. Garcia, R&D Lead

6. Request a Quote

Optimize your product with premium-grade TBSF. Contact our team for:

  • Custom purity (98-99.9%)
  • Bulk pricing (1kg to ton-scale)
  • Technical support

Email: info@vivalr.com
Tel: (86) 15866781826

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