4,4′,4”-Tris(carbazol-9-yl)-triphenylamine (CAS 139092-78-7) Technical Guide
Table of Contents
1. Product Overview & Specifications
Chemical Name: 4,4′,4”-Tris(carbazol-9-yl)-triphenylamine
CAS Number: 139092-78-7
Synonyms: Tris(4-carbazol-9-ylphenyl)amine; TCTA
Physical Properties:
- Molecular Weight: 765.88 g/mol
- Melting Point: 298-300°C
- Density: 1.234 g/cm³
- Refractive Index: 1.718
2. Key Applications
- OLED Fabrication: Hole-transport layer (HTL) material for organic light-emitting diodes.
- Exciplex Systems: Paired with electron-deficient materials (e.g., APDC-tPh) to generate near-infrared (NIR) emissions (700-730 nm).
- Research & Development: Used in optoelectronic studies for energy-level tuning and charge transport optimization.
3. Performance Comparison
| Parameter | TCTA | TXO-TPA | NPB |
|---|---|---|---|
| Emission Wavelength (nm) | 730 | 704 | 460 |
| Max EQE (%) | 0.1 | 1.27 | 5.2 |
| Thermal Stability (°C) | 300 | 280 | 250 |
Note: EQE = External Quantum Efficiency
4. Use Cases in OLED Technology
Case 1: NIR OLED Development
TCTA was combined with APDC-tPh to create an exciplex-based OLED emitting at 730 nm. While efficiency remains low (0.1% EQE), this system demonstrates potential for non-invasive biomedical imaging devices.
Case 2: Hole-Transport Layer Optimization
In multilayer OLED stacks, TCTA improves hole injection efficiency by 18% compared to conventional materials, reducing operating voltage by 0.3V.
5. Client Success Stories
PhotonTech Innovations (Shenzhen, China)
Integrated TCTA into flexible OLED prototypes, achieving a 15% improvement in device lifetime under high humidity (85% RH).
Luminex Display Solutions (Seoul, South Korea)
Utilized TCTA as a host material in blue OLEDs, achieving a color purity of 98.5% NTSC and power efficiency of 12 lm/W.
6. Request a Quote
For pricing, technical datasheets, or custom synthesis inquiries:
- Email: info@vivalr.com
- Tel: (86) 15866781826


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